Get to know your STKY chemicals (H2S)

While wrapping up a 2023 project, I was saddened to see the image below while in the OSHA incident database.  Several things come to mind regarding these H2S incidents:

1) no other chemical in the database has this deadly percentage over the past three (3) years

2) Hydrogen Sulfide has GREAT warning properties (odor threshold 0.008 to 0.1 ppm), but with that also comes Olfactory Fatigue (@ 100 ppm)

3) One might suspect these were Permit-Required Confined Space accidents, but many occurred outside a PRCS

4) Several of the deaths were due to H2S being a FLAMMABLE GAS; yes, H2S is both HIGHLY TOXIC and EXTREMELY FLAMMABLE

And the one thing that may be a driver of these deaths…

5) in the vast majority of these deaths, the H2S was CREATED NATURALLY.  It was not released from a cylinder/container for shipping or storage of H2S!

# Summary Nr Event Date Report ID Fatality NAICS Event Description
1 154242.01 02/24/2023 0830300 X 213112 Employee Is Killed In Confined Area Due To Overexposure To V
2 149915.01 09/19/2022 0627500 X 541620 Employee Is Killed While Pumping Waste Water
3 149136.01 08/22/2022 0522300 X 562211 One Employee Is Killed And Three Employees Are Injured When
4 147970.01 06/26/2022 0653510 X 213112 Two Employees Are Killed Inside Tank Due To Hydrogen Sulfide
5 146891.01 06/07/2022 0452110 X 221112 Employee Dies From Inhalation Of Hydrogen Sulfide
6 146481.01 05/14/2022 0627510 X 484110 Employee Is Killed And Two Employees Incur Burns When Ignite
7 145866.01 11/26/2021 0951510 X 221320 Employee Dies Of Natural Causes In Permit-Required Confined
8 145747.01 10/28/2021 0653510   213111 Employee Is Burned When Hydrogen Sulfide Gas Ignites
9 139143.01 09/12/2021 0453710 X 311613 Two Employees Are Killed When Overcome By Hydrogen Sulfide
10 139073.01 08/29/2021 0950411 X 811198 Two Employees Are Killed By Hydrogen Sulfide Exposure
11 138824.01 08/27/2021 0551800 X 447110 Employee Is Killed When Exposed To Hydrogen Sulfide
12 136167.01 06/08/2021 0213600 X 237310 One Employee Is Killed And Another Experiences Health Issues
13 136124.01 06/07/2021 0521100 X 541990 Employee Is Killed When Overexposed To H2s During Confined S
14 136332.01 05/25/2021 0653510 X 562212 Two Employees Are Killed From Overexposure To Gas In Vault
15 128141.01 07/24/2020 0626000 X 237110 Four Employees Are Exposed To Hydrogen Sulfide Gas; One Empl
16 127680.01 07/09/2020 0626600 X 562998 Two Employees Are Asphyxiated In Sewer Line Manhole
17 126541.01 05/29/2020 0454722 X 221310 Employee Is Killed After Overexposure To Hydrogen Sulfide/Dr

 

Source:  https://www.osha.gov/ords/imis/AccidentSearch.search?acc_keyword=%22Hydrogen%20Sulfide%22&keyword_list=on

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