Bryan Haywood

Can we use ACGIH TLVs/NIOSH RELs in the MUC formula rather than OSHA’s PELs?

The simple answer is yes, we can use ACGIH TLVs or NIOSH RELs to calculate the Maximum Use Concentration (MUC), but with one ABSOLUTE regulatory caveat: The resulting limit must be more protective (stricter) than what the OSHA standard dictates, or be applied to a chemical that OSHA does not currently regulate. Under 1910.134(b), OSHA…...

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The challenges of QUENCHING an MMA Polymerization event

For those curious, it will take around 27 pounds of Phenothiazine (PTZ) to successfully QUENCH the reaction, or, as some may call it, “short-stopping”. But these events usually occur in a “process vessel” that has an agitator. These tanks in CA do NOT appear to have agitators; however, they may be able to “mix” the…...

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MMA and the DOT Emergency Response Guide (ERG)

A lot of folks are angry that they have been forced from their homes, especially over a holiday weekend when families travel to visit families. I understand their anger, and I applaud the OCFA for their communication efforts to explain their decisions. So, for those of you who do not live and work in the…...

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Critical Temps for MMA

We keep hearing all these different temps from the media and OCFA. I am pretty sure they are both using Farenheit and Celsuis interchangably in their remarks and this can be confusing as heck. I just heard a media update state that “50 degrees is the happy place” for MMA. 50°F is the Flash Point…...

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Methyl Methacrylate (MMA) – CAS # 80-62-6

Methyl Methacrylate (MMA) is a flammable liquid used to manufacture plastics and resins. While it is regulated by OSHA and the EPA for occupational safety and toxic release reporting, it is currently NOT included on the EPA’s Risk Management Program (RMP) regulated list. It is a PSM Covered Chemical with a TQ of 10,000 pounds. MMA monomer weighs approximately 7.84 pounds per…...

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Explaining a Polymerization Event (Gemini+)

An uncontrolled polymerization event in a Methyl Methacrylate (MMA) storage tank is a classic, catastrophic thermal runaway scenario. When the monomer begins linking into polymer chains, the system enters a self-accelerating feedback loop that can rapidly overwhelm the vessel’s pressure-relief systems, leading to a violent rupture that often resembles a Boiling Liquid Expanding Vapor Explosion…...

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MMA Tank(s) Facility Siting

5/29/262 UPDATED using NFPA 30, Tables 22.4.1.5 and 22.4.1.1(b). It was brought to my attention that CA has more stringent requirements, so I have updated my post using NFPA 30, Chapter 22 – Storage of Ignitible (Flammable or Combustible) Liquids in Tanks — Aboveground Storage Tanks. My previous post was using IFC Tables. Using Google…...

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Although Flammable Gas codes/standards do NOT require the process to be “grounded”, grounding and bonding are ABSOLUTELY needed when purging/venting

While routine, closed-loop transfers are inherently safe from internal static ignition, bonding and grounding become critical whenever the system is opened to the atmosphere or when specific maintenance activities generate massive static charges. When we break the closed loop or introduce external energy, the hazard profile shifts from NFPA 58 back to the static mitigation…...

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How much NH3 is needed to achieve 16% by volume in a space that is 40′ x 40′ x 20′?

This post is a follow-up to my earlier post about NH3 being a CAT 2 Flammable Gas, as there are still businesses that dont fully grasp the full hazard profile of NH3. The fact that the facility is under the OSHA/RMP TQ of 10,000 pounds has NOTHING to do with needing the engine/mechanical room to…...

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Cheat Sheet for % by Volume vs Parts per Million (ppm)

The fundamental conversion rule is that 1% equals 10,000 ppm. Here is the conversion table scaling down from a completely pure atmosphere (100%) to a microscopic trace (1 ppm)…. Membership Required You must be a member to access this content.View Membership LevelsAlready a member? Log in here...

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MI inspection failures and failure to abate recognized deficiencies lead to Life-Altering Injuries and $350K in citations

A company has been fined £350,000 after the catastrophic collapse of a storage tank at its premises, which left a self-employed worker with life-changing injuries. The Health and Safety Executive (HSE) investigated the incident, which occurred on 21 June 2023 at an offshore supply base. The base handles around two thousand ship movements per year,…...

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