Another WRONG material to WRONG tank incident

At a brewery in 1997, an operator confused filling nozzles for two commonly used acid cleaning agents and transferred nitric acid into a tank with P3, a proprietary phosphoric acid based cleaner that also contained 5-15 percent isopropanol. 10-15 minutes later the mixture exploded violently. The stainless steel tank disintegrated with such force that fragments lodged in walls of concrete. The explosion ravaged the cellar, destroyed equipment, blew out a masonry wall and released large amounts of nitrous oxide fumes. Likely, 62 percent nitric acid (CAS 7697-37-2) and isopropanol (2-propanol, CAS 67-63-0) reacted to produce isopropyl nitrate (nitric acid 1-methylethyl ester, CAS 1712-64-7), a rocket propellant. It is argued that the accident has broad learning potential because of the widespread usage of the two chemicals across industries, the innocent nature of the human error and the severity of the consequence.  CLICK HERE to read report.

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