Chemical Process Safety (PSM/RMP)

Worker burned after safety failures triggered a violent LPG release at a shipping terminal

A ship’s engineer sustained cold burns to 10–13% of his body surface after liquid propane was released without warning in the early hours of 1 November 2018 during loading operations. A flammable gas cloud could have resulted in a catastrophic explosion if ignited. The worker was treated at the hospital and subsequently repatriated to Russia,…...

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Using 35°F – 50°F dew point compressed air in Hot Oil Boiler piping pressure/leak tests is a serious FAILURE

We get so much slack when we push Hydrostatic Pressure/Leak Testing vs. Pneumatic testing. So many think that pneumatic is easier and cheaper, when in reality it is NOT. In fact, the B31 series makes it clear that HYDROSTATIC is the first choice for pressure and leak testing. The code makes it clear that pneumatic…...

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Facility Siting 101 – Spacing of Flammable Liquid Storage Tanks (updated with MMA event)

OSHA, IFC, and NFPA have “separation distance” requirements for flammable liquid storage tanks. These requirements have been around longer than I have been dealing with hazardous materials and process safety, and yet we always come across some wildly out of “compliance” arrangements of these flammable liquid tanks. using OSHA’s Flammable Liquid Standard 1910.106 we can…...

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Explaining The “Solidification” Temperature Reality inside the MMA Tank in CA

The Fire Chief was talking about the phase change occurring inside the MMA tank. These are the critical temps for that to happen…. Membership Required You must be a member to access this content.View Membership LevelsAlready a member? Log in here...

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I wondered when the MMA tanks were installed in Garden Grove, CA

So I went back in time using Google Earth, and the last clear image was on June 1, 1994, and the three (3) tanks were present. Now, I have no idea if they were being used for MMA at that time. But the three (3) tanks were present, along with the larger tank next to…...

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CalARP Program 4 (Refineries)

Following the 2012 Chevron Refinery Fire, California created an Interagency Refinery Task Force (IRTF) headed by CalEPA, with participation from the Department of Industrial Relations and 11 other federal, state, and local agencies and departments. The purpose of Program 4 is to prevent major incidents at petroleum refineries to protect the health and safety of…...

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Vacuum destroys more vessels than over-pressure events

Not sure why “Over Pressure” events get all the attention. It is my belief that we destroy more vessels each year due to a vacuum than we do with over-pressure events. Of course, overpressure events have more layers of protection because they pose far greater risks. In my career, I have seen these failures occur…...

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MMA Storage Tanks Design

Storing Methyl Methacrylate (MMA) requires a delicate engineering balance. Because it is both a Class IB Flammable Liquid and a Class 2 Unstable Reactive, the storage design must simultaneously mitigate the vapor-fire hazard while actively feeding the chemical inhibitor to prevent thermal runaway. When evaluating bulk storage tanks from a Process Safety Management (PSM) perspective,…...

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The challenges of QUENCHING an MMA Polymerization event

For those curious, it will take around 27 pounds of Phenothiazine (PTZ) to successfully QUENCH the reaction, or, as some may call it, “short-stopping”. But these events usually occur in a “process vessel” that has an agitator. These tanks in CA do NOT appear to have agitators; however, they may be able to “mix” the…...

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Critical Temps for MMA

We keep hearing all these different temps from the media and OCFA. I am pretty sure they are both using Farenheit and Celsuis interchangably in their remarks and this can be confusing as heck. I just heard a media update state that “50 degrees is the happy place” for MMA. 50°F is the Flash Point…...

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Methyl Methacrylate (MMA) – CAS # 80-62-6

Methyl Methacrylate (MMA) is a flammable liquid used to manufacture plastics and resins. While it is regulated by OSHA and the EPA for occupational safety and toxic release reporting, it is currently NOT included on the EPA’s Risk Management Program (RMP) regulated list. It is a PSM Covered Chemical with a TQ of 10,000 pounds. MMA monomer weighs approximately 7.84 pounds per…...

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Explaining a Polymerization Event (Gemini+)

An uncontrolled polymerization event in a Methyl Methacrylate (MMA) storage tank is a classic, catastrophic thermal runaway scenario. When the monomer begins linking into polymer chains, the system enters a self-accelerating feedback loop that can rapidly overwhelm the vessel’s pressure-relief systems, leading to a violent rupture that often resembles a Boiling Liquid Expanding Vapor Explosion…...

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