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Methyl Methacrylate (MMA) - CAS # 80-62-6
Methyl Methacrylate (MMA) is a flammable liquid used to manufacture plastics and resins. While it is regulated by OSHA and the EPA for occupational safety and toxic release reporting, it is currently NOT included on the EPA’s Risk Management Program (RMP) regulated list. It is a PSM Covered Chemical with a TQ of 10,000 pounds. MMA monomer weighs approximately 7.84 pounds per gallon; meaning...
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EPA RMP citations @ renewable energy facility (Isobutane & $12K)
Following its September 19th-20th, 2024 inspection, EPA alleges Respondent’s failure to: … HomeRead More »
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Explaining a Polymerization Event (Gemini+)
An uncontrolled polymerization event in a Methyl Methacrylate (MMA) storage tank is a classic, catastrophic thermal runaway scenario. When the monomer begins linking into polymer chains, the system enters a self-accelerating feedback loop that can rapidly overwhelm the vessel’s pressure-relief systems, leading to a violent rupture that often resembles a Boiling Liquid Expanding Vapor Explosion...
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MMA Tank(s) Facility Siting
5/29/262 UPDATED using NFPA 30, Tables 22.4.1.5 and 22.4.1.1(b). It was brought to my attention that CA has more stringent requirements, so I have updated my post using NFPA 30, Chapter 22 – Storage of Ignitible (Flammable or Combustible) Liquids in Tanks — Aboveground Storage Tanks. My previous post was using IFC Tables. Using Google Maps and Information from the Fire Authority dealing...
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Although Flammable Gas codes/standards do NOT require the process to be “grounded”, grounding and bonding are ABSOLUTELY needed when purging/venting
While routine, closed-loop transfers are inherently safe from internal static ignition, bonding and grounding become critical whenever the system is opened to the atmosphere or when specific maintenance activities generate massive static charges. When we break the closed loop or introduce external energy, the hazard profile shifts from NFPA 58 back to the static mitigation principles found in NFPA...
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How much NH3 is needed to achieve 16% by volume in a space that is 40' x 40' x 20'?
This post is a follow-up to my earlier post about NH3 being a CAT 2 Flammable Gas, as there are still businesses that dont fully grasp the full hazard profile of NH3. The fact that the facility is under the OSHA/RMP TQ of 10,000 pounds has NOTHING to do with needing the engine/mechanical room to be “adequately ventilated” in order to exempt the space from being a Class 1, Div 2, Group...
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Cheat Sheet for % by Volume vs Parts per Million (ppm)
The fundamental conversion rule is that 1% equals 10,000 ppm. Here is the conversion table scaling down from a completely pure atmosphere (100%) to a microscopic trace (1 ppm). … HomeRead More »
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MI inspection failures and failure to abate recognized deficiencies lead to Life-Altering Injuries and $350K in citations
A company has been fined £350,000 after the catastrophic collapse of a storage tank at its premises, which left a self-employed worker with life-changing injuries. The Health and Safety Executive (HSE) investigated the incident, which occurred on 21 June 2023 at an offshore supply base. The base handles around two thousand ship movements per year, supplying North Sea oil and gas installations with...
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Updates to NFPA 704, 2027 - Some flammable gases will be a "3" rather than a "4" based on their fundamental burning velocity
The 2027 edition of NFPA 704, Standard System for the Identification of the Hazards of Materials for Emergency Response, includes new definitions of the terms “battery energy storage system” and “lithium-based battery,” along with associated annex material. Updates have been made in Section 6.2, Degrees of Hazards for Flammability Hazards, to align with NFPA 1 regarding Category...
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Updates to NFPA 497, 2027
NFPA has updated its NFPA 497, Recommended Practice for the Classification of Flammable Liquids, Gases, or Vapors and of Hazardous (Classified) Locations for Electrical Installations in Chemical Process Areas, with a few minor revisions. Probably the most significant revision is NFPA’s position on “intentional releases and maintenance venting.” The most beneficial revision was NFPA...
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NFPA 30 and NFPA 497 HAZLOCs... why are the two different?
In the 2027 edition of NFPA 30, the standard now provides a NEW schematic illustrating the spatial layout of hazardous (classified) locations for indoor areas with process equipment containing ignitible (flammable or combustible) liquids at pressures of 100 psig or less. I am not sure why they included this in NFPA 30 (Chapter 7) or why the new schematic differs from that in NFPA 497, but I will discuss...
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Understanding "fundamental burning velocity of less than 10 cm/s" with Category 1B Flammable Gases
The new means to analyze risks associated with flammable gases is their “burning velocity,” and the new limit is 10 cm/s. So I wanted to provide some real-world examples of what this looks like. So I asked AI to compare 10 cm/s flame front with the speed of a person walking and a jackrabbit. OSHA defines a CAT 1B Flammable gas as: Gases which meet the flammability criteria for Category...
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