Chemical Process Safety (PSM/RMP)

Anhydrous Ammonia Pipe Welding per ANSI K61.1/CGA 2.1 (ASME B31.3)

2019 has been a year of coal-fired power plants or me so far!  It’s only June and I have spent more than four weeks in these facilities.  With that said, I wanted to provide my friends in that industry who operate an SCR some factual information on their Anhydrous Ammonia (NH3) piping and what ANSI K61.1/CGA…...

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North Dakota’s Anhydrous Ammonia Code – well done ND!

The state of North Dakota has an excellent state code for Anhydrous Ammonia.  They have done so much more than just adopted ANSI K61.1/CGA 2.1.  They have written a code for a process safety novice, using the RAGAGEPs as their foundation…. Membership Required You must be a member to access this content.View Membership LevelsAlready a...

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Accidents associated with ammonia (ARIA)

This study essentially concerns refrigeration installations using ammonia as a refrigerant.  However, in order to better understand and to place the risks associated with these installations in perspective, quantified information has also been collected on numerous accidents, both French or foreign, in other industrial or agricultural activities and in the field of transport. The processing of these data allows…...

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Explosion of an alcohol tank inside a vinegar plant

Inside a vinegar plant, a 150-m³ tank containing 38.5 m³ of an alcohol vinegar mixture exploded around 9:40 am. The 3,000-m² site had been in activity start-up mode, but engineering works were still underway. The tank bottom became detached from the shell. It’s upper part, measuring 13 m high, 4 m in diameter and weighing some 3.5 tonnes, was…...

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Hydrogen chloride release following a maintenance operation

Ten kilos (22 pounds) of hydrogen chloride gas was released from a flange that had been fitted by a contractor just a few weeks earlier, triggering alarms and resulting in an internal emergency intervention. The incident had no significant consequences.  A contractor performing maintenance was instructed to remove the pressure sensor from a device and replace it with…...

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Explosion of an underground solvent storage tank during a maintenance operation

A contractor at an upper-tier Seveso plant was cleaning an underground tank so that it could be filled with a different product. The tank was located in an outdoor area comprising 12 horizontal underground multi-compartment tanks, each having an overall capacity of 60 m³ (nominal compartment capacities of 10, 15 and 35 m³) and containing flammable liquids (solvents…...

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Phosgene discharges in a chemical plant (IMPEL)

At around 11:00 p.m., phosgene (COCl2) and chlorobenzene began leaking inside the containment building of a chlorinated chemicals plant. The leak was detected at levels between 13 and 22 ppm by analyzers inside the containment. The analyzers’ control system automatically directed the air inside the containment towards the caustic scrubber. Technicians began looking for the cause of the leak.  While one of…...

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The use of sulfur stick to find a CAT 2 Flammable Gas Leak comes with some inherent hazards (Video)

The irony in this post is thick with sulfur smoke! SAFTENG Members can read my 2012 article Sulfur sticks and ammonia leaks… are you in compliance when using these leak detection devices? This video shows us what happens when we introduce a lit sulfur stick into an NH3 gas leak.  Imagine someone doing this in a…...

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Process Safety MANAGEMENT

Words still mean something!  There is a reason why OSHA (and EPA) use the word “Management” in the titles of their process safety standards.  Sorry to state the obvious, but the standards are NOT called “process safety managER” for a really good reason.  I have been serious about process safety since 1993 and the one…...

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Anhydrous Ammonia Exposure Event (Line Break Gone Bad – RV change out @ power plant)

An ammonia storage tank was taken out of service for its 10-year non-destructive examination. After the tank was purged and opened, two (2) contractors were removing two (2) relief valves for their 5-year inspection and tests. The two (2) relief valves are 8 bolt flanged connected to a wye piping fitting equipped with a selector valve (as…...

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Anhydrous Ammonia nitrogen stabilizers need an MOC and PSSR in the fertilizer industry

Back in December 2017, I wrote about a change in the Anhydrous Ammonia fertilizer industry that would most likely require the industry to perform an MOC and PSSR. (A new grade of anhydrous ammonia fertilizer means a MOC, PSSR, etc.)  Now that the product has received its official approval and has found its way into the…...

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Workers Hospitalized from Ammonia Leak during PRV Maintenance (Line Break/Process Opening Gone Bad @ food plant)

In April 2011, an OSHA State Plan investigated a 3,600-pound ammonia release at a large warehouse where anhydrous ammonia is used in the refrigeration system in a cold storage building. In this incident, one worker was burned on the arm from the escaping gaseous ammonia. As part of the planned mechanical integrity schedule, two (2) employees…...

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