Hazardous Materials

Just when you thought it was safe… Chlorine can kick your a_ _!

Two of my major chemical incidents in my career occurred during “demo work” in a process that we were certain was gas-free/zero energy state.  And of course, we were wrong!  Highly toxic/flammable gases can travel long ways to places we never thought possible and do some serious damage to people and property when they get…...

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Bonding and Grounding flammable gas systems, why NFPA and OSHA don’t require it

I am going to bet that if you’re reading this article that your facility has a flammable gas that gets transferred from one container to another.  And I will also bet that these transfers are done under the safety blanket of “bonding and grounding” as we do for our flammable liquids.  But did you know,…...

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The state of IL and Ammonia fertilizer process design

In light of the recent EPA citation at a bulk storage facility for anhydrous ammonia (NH3) I thought it would be fitting to highlight a best practice from the state of Illinois for this type of process.  Most states are in the process of updating their state codes for the safe storage and handling of…...

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Isobutane and your LEL sensor’s correction calculation

If you have read your meter’s manual you have most certainly come across it’s “correction calculation”, usually in the back of the manual.  But Isobutane is not a common flammable, so why did it make it on the list of those popular flammables?  It is because of the “green movement”… yes, Isobutane (R-600a) is a…...

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Anhydrous Ammonia Emergency Shutdown for Hose Severance

In the past 2-3 years, I have begun seeing Anhydrous Ammonia systems that claim to be built to ANSI K61.1 or CGA 2.1, but somehow these processes do not have the Emergency Shutdown Systems required by these two Recognized and Generally Accepted Good Engineering Practices.  So with the help of the Illinois Fertilizer & Chemical…...

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Anhydrous Ammonia unloading and tank requirements in laymen terms

My previous article on the Anhydrous Ammonia requirements generated a lot of questions, mostly about how OSHA worded their requirements when it came to Excess Flow Valves, Check Valves, Unloading, and Emergency Shutoff Valves.  So this posting I used one of my favorite sources, WA States LNI standards, to present the material in a more…...

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Anhydrous Ammonia unloading design specs in 1910.111

This article is being posted in my Hazardous Materials section rather than the Process Safety section because the vast majority of my finds regarding the lack of proper design are almost exclusively in processes that have less than 10,000 pounds.  I am hoping that those who read this will understand that what I am going…...

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When bollards fail!

All bollards have limitations.  Most are designed to stop a 12,000-pound vehicle traveling at 10-mph.  Most non-commercial vehicles will weigh far less than 12,000 pounds; however, 18-wheelers will weigh far more than 12,000-pounds.  These are the bollards that are the ones that are 4″ steel pipes filled with concrete and buried at least 3′ into…...

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Fueling stations, bollards and fake bollards

Anyone who follows my ramblings knows that I am a big fan of bollards.  I have written about them and shared dozens of incidents where a properly designed and installed bollard saves the day and more often than not I am sharing incidents with “fake” bollards where something was destroyed because the bollard was IMPROPERLY…...

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Where does it require I have an Oxygen Monitor when I use liquid Nitrogen?

OSHA may use their General Duty Clause (GDC) to enforce their desire for employers to have Oxygen monitor(s) in areas where inert cryogenics are stored and used.  But I like to use codes/standards (e.g. RAGAGEPs) to drive my safety engineering of these hazardous processes, even though they are not PSM/RMP covered processes.  To do this…...

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Liquid Nitrogen and the IFC (Part I)

This week we saw OSHA issue two willful and three serious violations totaling $122,602 to a sperm bank for bulls (cattle) after an employee was asphyxiated while filling freezers with Liquid Nitrogen.  And back in 2017, we saw another sperm bank, this one for humans, have a Nitrogen incident which claimed the life of a…...

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Alarming Trends Found on Fixed Gas Detection Systems (USCG Safety Alert)

The United States Coast Guard issued a Marine Safety Alert after they discovered three (3) separate Liquefied Natural Gas (LNG) carriers with issues with their fixed flammable gas detection systems that resulted in the issuance of deficiencies and delay of cargo operations. While witnessing tests, multiple sensors measured outside the tolerances established by the manufacturer…...

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