Hazardous Materials

The scienece behind “Scrubbing Cl2 in NaOH”

As with my NH3 article, I wanted to verify and document the same scenario for scrubbing 1 pound of Cl2 with 50% Sodium Hydroxide (NaOH). Here is what Gemini+ had to say… When Chlorine (Cl2) gas is safely scrubbed with Sodium Hydroxide (NaOH), the reaction produces sodium hypochlorite (bleach), sodium chloride (salt), and water. Bottom…...

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The scienece behind “Scrubbing NH3 in water”

Throughout my career, I have been taught that to safely “scrub” 1 pound of NH3, 1 gallon of water is required. I have firsthand experience in this ratio working. So I decided to ask Google Gemini+ to explain this ratio. Looking back at IIAR-2, when we sized a Diffusion Tank for PSV discharge(s), it was…...

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Why we want to ALWAYS Hydrostatically Test our chemical hoses vs. Pneumatically Testing

As I have written many times, our bulk chemical transfer hoses MUST be part of an Inspection and Testing Program. These tests follow the same logic as pressure testing piping, and Hydrostatic Testing is far safer than pneumatic testing. So I asked Google Gemini+ to show me the difference in failure energies to demonstrate this…...

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Pressure Wave generated by a 1,000 Liter (264 gallons) N2 Dewar catastrophically failing

To determine the internal static overpressure generated by the catastrophic failure of a liquid Nitrogen (LN2) dewar, we look at the physics of a Boiling Liquid Expanding Vapor Explosion (BLEVE) and the resulting rapid phase transition…. Membership Required You must be a member to access this content.View Membership LevelsAlready a member? Log in here...

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Pressure Wave generated by a 1-ton Cl2 cylinder catastrophically failing (WCS for Cl2 1-ton cylinder inside a Cl2 building)

So I asked Google Gemni + to calculate the pressure wave in a room that is 40′ X 40′ X 20′ tall with the catastrophic failure of a 1-ton chlorine cylinder. In a 32,000 ft3 room, we must determine the volume of gas released during the “instantaneous flash” and the resulting internal static overpressure…. Membership...

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I have created a “cheat sheet” for safe distances during pneumatic pressure testing (ASME PCC-2, Mandatory Appendix 501-III)

DISCLAIMER: This is a “cheat sheet” for safety professionals to get a general idea of the “safe distances.” ALWAYS refer to ASME PCC-2, Mandatory Appendix 501-III) for the exact distance. Just understand, ALL pneumatic pressure testing REQUIRES a “safe distance”. According to ASME PCC-2, Mandatory Appendix 501-III, determining safe distances for pressure testing—specifically, pneumatic testing—requires…...

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NFPA’s Tentative Interim Amendment (TIA) 27-1 – 2027 Edition of NFPA 30

Tentative Interim Amendment (TIA) 27-1 refers to a significant update to the 2027 Edition of NFPA 30: Flammable and Combustible Liquids Code. Issued on April 15, 2026, with an effective date of May 5, 2026, this TIA (Log #1886) was processed by the Technical Committee on Flammable and Combustible Liquids to address safety gaps regarding…...

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What is a Hierarchy of Hazard Control Analysis (HCA)?

Under Cal/OSHA’s Process Safety Management (PSM) standards (specifically Title 8 §5189.1 for refineries and §5110.16 for other facilities), the Hierarchy of Hazard Control Analysis (HCA) is a formal, documented requirement that goes significantly beyond the traditional OSHA “inverted pyramid.” While standard safety protocols often treat the hierarchy as a suggestion, Cal/OSHA makes it a mandatory…...

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Key Changes in the 2027 Edition of NFPA 30: Flammable and Combustible Liquids Code

The 2027 edition of NFPA 30 introduces significant structural and technical updates designed to improve clarity, streamline protection requirements, and integrate emerging safety technologies. Here are the primary changes professionals need to know…. Membership Required You must be a member to access this content.View Membership LevelsAlready a member? Log in here...

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The history of H2S’s IDLH Limit

The Evolution of the Hydrogen Sulfide IDLH: From Lethality to Escape Impairment The history of the Immediately Dangerous to Life or Health (IDLH) value for Hydrogen Sulfide (H2S) reflects a critical evolution in industrial safety. It highlights a shift from focusing purely on survival to understanding the physiological “tipping points” that prevent a worker from…...

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The history of Br’s IDLH Limits

The Immediately Dangerous to Life or Health (IDLH) history for bromine follows a trajectory similar to that of chlorine, though the data pool has historically been smaller, leading to greater reliance on comparative toxicology…. Membership Required You must be a member to access this content.View Membership LevelsAlready a member? Log in here...

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The history of Cl2’s IDLH Limits

The Immediately Dangerous to Life or Health (IDLH) value for chlorine has been subject to significant reevaluation since its inception in the 1970s. The history reflects a transition from an early consensus on occupational safety to more rigorous, data-driven toxicological assessments…. Membership Required You must be a member to access this content.View Membership LevelsAlready a...

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